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Polaris loves Powder but also strongly wishes they weren't sisters sometimes. Powder is much more successful in her modelling career than Polaris is. Polaris finds that she's being overshadowed by her sister and that she'll never get her secondary career off the ground.
Powder thinks that her little sister is extremely talented and she's glad that someone took on helping her Step-Mother's business. Other than that, they have a bit of a sibling rivalry going on, since they both do modelling on the side. Magazines compare them a lot, and so do they. They're both constantly questioned about the other as well.
Star adores her boyfriend and finds his con work genuinely fascinating. He really thinks up these amazing plots every day? It impresses her so much how smart her love is. She writes to him whenever she has the time or when something new and exciting happens.
Rabbit's Eye only has eyes for his lovely, Starfruit. He genuinely thinks that Star is the most beautiful mare in the world. He writes her letters and counts the days until he can see her again. He travels for his work so often that he's rarely back in either Ponyville or Canterlot these days...even more rarely Canterlot due to the guard presence there.
Harlequin used to really look up to their older sister, now he struggles with his emotions towards her. She's accepted by all three of her moms/parents... he doesn't think about it too hard. He also really struggles with Jawbreaker's motherly attitude towards him, as he doesn't really get along with Pinkie Pie either and Jawbreaker's behavior triggers his feelings with that. Instead of communicating this though, he tends to blow up at his sister instead.
Quinn likes his sister, Jammy. He thinks that her unstableness is a little unnerving, but that her powers could be used for his goal one day... but the hard part would be getting her to care. He gets so frustrated how little she cares about her siblings day to day affairs.
Quinn struggles with his older brother, as well. Jack tries to be Quinn's friend a lot, and tries helping him with whatever he's doing whenever he isn't busy... but Quinn's paranoia gets in the way of this. He tends to scream at Jack to leave him alone and hurts his feelings it seems... Quinn feels bad for this, but won't allow himself to relax either.
Hairspray adores messing with his little sister's mane. She's a bit of a diva when it comes to it's perfection, but he's willing to accept that and the berating that comes with it if it isn't perfect. He loves his little sister too much to hold it against her... or her mane.
Fantasia likes her older brother, and loves letting him and her dad style her mane before shows. She prides herself on her appearance and doesn't like anyone to see her on a bad mane day, so she's taken some verbal aggression out on her brother and father several times.
Constance and Little Dipper are really, really different. Personality and appearance wise. Their parents find it odd due to them sharing a parental pair, but things happen! Constance really doesn't know how to interact with their brother, Dipper. She finds him to be a little bit boring, not nearly like Umbriel though.
Dipper thinks that Constance is doing the supervillain thing as a bit and thinks it's super cool how she doesn't ever break character.
Blood Sugar genuinely hates her sister, Love Potion. She thinks that she's the biggest hypocrite ever and hates how judgmental she is. How dare she judge her for putting her fashion out for ponies, it's not vain- it's business?
Potion thinks her sisters fashion is tacky and only for queer ponies to enjoy, which she dislikes. She throws a fit whenever her sister refuses to make her clothes, which of course she demands for free since they're sisters.
Constance thinks that her little sister is pretty cool and would spare her in the case of total world domination. She wants to get closer with her as well, but isn't sure where to start. Instead, she keeps to herself and is too anxious that her sister won't want to be her friend.
Starfruit wishes that her older sister was a bit more...feminine. Nothing against her look or personality of course! She just wishes she had an older sister that she could gossip with and have makeovers with. Constance doesn't even attend any of the galas- she just claims that "a supervillain, like myself, would never be caught dead in a frilly gown." and this has strongly discouraged Starfruit from trying to reach out to her sister about becoming closer. Does Starfruit think her sister is a little nuts? Yes, yes she does.
Dipper likes his little sister, but struggles to interact with her outside of dinner and family game nights. (These are mandated by Twilight btw, Luna and Mac also don't particularly like it, but love Twi and put up with it.) They usually end up joining teams with Momma Luna and going after Umbriel and Starfruit's team though, so they at least have their family game night rivalry.
Starfruit and Little Dipper have a distant relationship, they don't dislike one another but they don't have a lot in common outside of being siblings. She thinks he's a little weird and stays out of his way.
Thrill...is unsettled by Harlequin. He's always up in his room or hanging out with his friend, Nimble Nectarine. He seems off 99% of the time, seemingly scheming something? They can't tell. They wish Quinn was still like his childhood self, and not a shell of a sibling.
Quinn tends to ignore Thrill's existence, simply due to focusing on his own goals. He wishes that his work didn't take him away from his family so much, as Thrill almost seems to wince whenever he's nearby. Harlequin wonders if this is because of his blow ups or if they've read his journal...
Thrill thinks their little sibling is super cool- and is super proud of them for never letting ponies try to change them. They're not a pony, so they get a lot of shit from assholes. Thrill has beat up a colt on the playground for their little sister, full sail.
Thrill and Jawbreaker have a joke sibling rivalry of sorts- aka, which pony is stronger than the other. They arm wrestle, work out at Sweet Apple Acres, etc... Thrill usually loses, but gets super pumped up by the time with their sister.
(they also smoke together lmao)
Thrill loves their older, goofy ass, brother. They occasionally smoke with one another after shows, which they do attend with one another! Jack is big into the alternative music scene and also into group settings. Thrill needs to be mellowed out by another pony at shows, or else it goes poorly. So, if they don't go with Live Wire or Over Yonder, they go with Jack!
Umbriel is strongly disappointed in Dipper, he thinks he's lazy and incapable of getting out of his own way. He wishes he would pull his head out of his ass and realize that he's a prince and his public image matters. He can't be out stoned all the time with his friends!
Dipper knows his siblings sternness comes from a place of love, but wishes that Umbriel would stop mother henning him. He already hears enough about his love for the devil's lettuce from his mothers and father.
Umbriel would defend their little sister with his life, if he had to. They adore Starfruit and spend as much time as they can with her. They always have, even now that she's an older teen, he checks up on her. If she needs anything, to vent, help with study-work, figuring out a spell- anything! Umbriel would come running at a drop of a hat if she needed it.
Starfruit adores Umbriel with every part of her body, he's the ultimate older sibling! He helps her with everything she needs and more, and she often rants to him about her love life...much to Umbriel's dismay.
Umbriel doesn't understand Constance at all, like, literally at all. She's odd and causes chaos for no reason other than to annoy ponies? Why? And why does she call herself a "supervillain", she's literally a princess?
Constance finds Umbriel insufferable and to be no fun. All work no play. Their most boring sibling.
Witch Hazel adores their little sibling, but from afar. She knows that they became more like their mother, Applejack, as they aged and is a little conservative appearing too due to this. She wishes they would come out of their shell more and open up about their real opinions! She knows for a fact that Yonder is morally and ideally nothing like AJ, but keeps up that facade for the family.
Yonder doesn't have any strong feelings towards their older sister. They think that her potion making is a little odd but if it makes her happy and fulfills her, who can really tell her it's not right for her?
Polaris struggles to be around Buzz, she thinks that Buzz thinks she's stupid. Polaris is quite intelligent all around, but can't get around her privilege of being a pretty unicorn mare in high society. She can't quite figure out how to put herself in her sisters horseshoes. But, she's trying to start advocating for the ponies in society who need their voices lifted, in honor of her sister. Whether she knows it or not.
Buzz thinks that Polaris is a bit of a ditz. Her sister constantly asks Buzz why she doesn't try harder to get more fashion shows or why she's advocating for the rights of hybrids when "they already have rights". Well, yes dear sister, on paper they do. But, Buzz has tried explaining to her several times that hybrids are treated different by others. Polaris explains that she doesn't personally notice or partake in that behavior. Which aggravates Buzz because, yes, yes you do girlie.
Powder thinks her sister is a bit odd, with her political beliefs and how vocal she is about it...she's mostly supportive, and she loves Buzz.
Buzz likes her older sister, but struggles with her at the same time. They have a large-ish age gap, think between 8-9 years. They're both very different, but still get along.
Harlequin hasn't really noticed Belladonna outside of being Shining's kid. He knows she isn't considered royalty and doesn't really care. Has lightly thought of recruiting her for his cause, but not strongly.
Belladonna has seen Harlequin before when she visits Ponyville, she suspects that they're siblings...based on appearance alone.