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Chang'e fell for Castelia a long time ago, after a couple of years of friendship. Their friendship was always important and cherished by Chang'e as well as something she so desperately hoped to elevate to a romantic relationship. After admitting her feelings there was no going back...
Chang'e and Ana are very friendly towards each other, usually spending some quality (and CALM) time together. Chang'e admired Ana for her enthusiasm and energy, and always feels cheered up immediately when around Ana's positive attitude.