Anjou is Nectar's best friend, and the co owner of her shop. While she handles all of the coffee related business, he's in charge of the pastries they serve. The two of them get along famously, and enjoy getting to see each other nearly every day.

Nectar knows Arbor by way of him being Anjou's boyfriend, but considers him to be a close friend all the same. The two of them are both mellow enough to be able to just exist in the same space without really saying anything. Nectar thinks he and Anjou are an adorable couple.

Xia lives in the same area as Nectar, and the two of them get along very well. They have similar interests, and both enjoy being around others, so it's not uncommon for them to band together and host a get together for all of their friends. They have a routine where they will exchange dinners once a week, alternating whose house they meet at.

Nectar runs into Xia's troublemaking younger sibling quite often, seeing as they're constantly over at their sister's. She thinks they're a funny and charming young bean, and enjoys their antics whenever they're around. Due to her close friendship with Xia, she tends to think of them as a younger sibling as well.

Nectar just sees her friends with their family and goes "it's free sibling." Just like Yingying, she considers Xia's youngest brother to be like a little brother to her as well. Although Xiao Gua can be prickly and isn't the type you'd expect someone like Nectar to get along with, she is equally as fond of him as the rest of his family, and thinks his grumpiness is sort of adorable.