OK japes aside I'll give you a real couple.
Cameron and Jackson. I mean, it probably won't work given that Jackson's into people significantly older than him and Cameron is stuck at 27 forever but I like the concept of cop x robber- especially such an elusive robber as the Master Thief! I see it playing out like a fun rivalry. Additionally both have had run-ins with Smiley before too and some sort of cool battle with them teaming up against him is a fun idea to imagine!